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    Projects»
    micro resist technology GmbH

     UV-curable materials for NIL

    Projekt Number
    IW050336
    funded by the Bundesministerium für Wirtschaft und Technologie [German Ministry of Economy and Technology – BMWi]

    Project duration
    1st March 2005 – 30th June 2007


    Project objectives
    The objective of the national project entitled “Entwicklung von UV-prägbar Polymersystemen für die Nanoimprint-Lithografie” [development of polymer systems which can be UV imprinted for nanoimprint lithography] was to develop nanopatternable polymer systems based on reactive, low-viscosity, cross-linkable components for UV-assisted nanoimprint lithography (UV-NIL). Industrial applications for nanoimprint lithography will arise in future for both thermal and UV-assisted imprinting, which was why micro resist technology GmbH launched this project in 2005 specifically to expand the principles of its existing leading-edge development and experience in nanoimprint polymers. As a consequence, micro resist technology GmbH as a material manufacturer can offer polymers and resists for both technology variants.

    Project benefit
    The main application under consideration was use as an etching mask for transferring patterns in metal or semiconductor substrates. Numerous customer enquiries relating to UV-NIL and the latest developments in suitable imprinting machines gave impetus to the decision to serve this promising market. Key factors in project progress were investigations into layer formation, flow characteristics during imprinting, UV curing, surface properties and plasma etching.
    Following thorough preparation, research work focused on qualifying a polymer system suitable for UV-NIL processes and this aim was achieved. Extensive investigations into various raw materials and their properties during the processing of thin layers, during imprinting and during UV curing led to several polymer systems for UV imprinting; from among these, mr-UVCur06 was qualified as a product. Tests conducted with our partner in the collaboration, AMO GmbH, confirmed excellent imprinting properties for this UV-NIL polymer. Both very low residual layers below 10 nm and pattern resolution down to the sub-30 nm range can be achieved. Its good flow properties also make it possible to fill and imprint patterns of several orders of magnitude simultaneously (sub-100 nm to 10 µm range). Curing speed on UV exposure has been increased to achieve UV-NIL process times in the range of a few seconds. Plasma etching processes have been evaluated for transferring patterns to common substrate materials.


    Outlook
    In the course of the project, several polymer systems with very good UV imprint properties were qualified. The first product from the material development of the project to be offered commercially is mr-UVCur06. The project results are a good basis for developing further materials for UV-NIL with modified characteristics, e.g. for the production of nanostructures in microelectronics or in data storage.

    Line patterns with resolutions to < 30 nm (Source: AMO GmbH)


    UV-NIL process with very short process time (17 s)


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